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Residuals: charmed (GI-style) ​

Model: with GI momentum-sandwiched smeared contact hyperfine (every L), fixed-sector L·S (vector+Thomas) and OGE-tensor diagonalization with GI momentum-factor sandwiches and smeared-G/S derivative kernels; GI Table II b, c, masses, ε factors, and Fig. 2 α_s(r); closed-form GI G̃(r), S̃(r), plus central Coulomb momentum sandwich A(p)G̃A(p) in the solver's native p² representation, see the GIModel package (src/ at the repository root) for the computation and GIPaper (GIPaper/src/) for the comparison layer.

Numerics: OscillatorSolver — nbasis = 24:8:80 adaptive, ΔE ≤ 0.1 MeV, beta in [0.25, 2.35] GeV (22 bracket points, refined to 0.002 GeV), 6 levels/channel.

statereference GeVbaseline GeVresidual MeVconfidence
1^1S_01.8801.874-6.4high
2^1S_02.5802.583+2.7high
1^3S_12.0402.038-1.9high
2^3S_12.6402.645+5.0high
1^3D_12.8202.816-3.5high
1^3P_02.4002.395-5.1high
1^1P_12.4402.456+15.7high
1^3P_12.4902.465-24.8high
1^3P_22.5002.502+2.0high
1^3D_32.8302.833+2.9high
1^3F_43.1103.113+3.0medium
1^1S_01.9801.974-5.8high
2^1S_02.6702.675+4.9high
1^3S_12.1302.125-5.3high
2^3S_12.7302.735+4.5high
1^3D_12.9002.899-1.5high
1^3P_02.4802.481+0.7high
1^1P_12.5302.547+17.4high
1^3P_12.5702.554-15.5high
1^3P_22.5902.591+1.1high
1^3D_32.9202.916-3.9high
1^3F_43.1903.190-0.2medium

Contribution Breakdown (diagnostic) ​

The central, contact, spin-orbit, and tensor columns are operator contributions in the same fully diagonalized fixed-sector eigenstate. They are not differences from a separate central-only solve.

statecentral contribution GeVcontact MeVL·S(vec) MeVL·S(Thomas) MeVL·S total MeVtensor MeVannihilation MeVspin + annihilation MeVpredicted GeV
1^1S_02.014-140.9+0.0+0.0+0.0+0.0+0.0-140.91.874
2^1S_02.627-44.4+0.0+0.0+0.0+0.0+0.0-44.42.583
1^3S_12.003+35.3+0.0+0.0+0.0+0.0+0.0+35.32.038
2^3S_12.629+16.2+0.0+0.0+0.0+0.0+0.0+16.22.645
1^3D_12.836+1.6-70.4+54.1-16.3-4.9+0.0-19.62.816
1^3P_02.486+7.7-133.3+58.0-75.4-23.6+0.0-91.32.395
1^1P_12.476-18.8+0.0+0.0+0.0+0.0+0.0-18.82.456
1^3P_12.477+6.3-61.0+30.3-30.7+11.1+0.0-13.32.465
1^3P_22.479+4.6+52.9-32.4+20.6-2.0+0.0+23.22.502
1^3D_32.833+1.0+39.1-39.0+0.1-1.2+0.0-0.12.833
1^3F_43.125+0.3+28.6-40.3-11.7-0.7+0.0-12.13.113
1^1S_02.104-130.1+0.0+0.0+0.0+0.0+0.0-130.11.974
2^1S_02.718-43.2+0.0+0.0+0.0+0.0+0.0-43.22.675
1^3S_12.093+32.1+0.0+0.0+0.0+0.0+0.0+32.12.125
2^3S_12.719+15.2+0.0+0.0+0.0+0.0+0.0+15.22.735
1^3D_12.917+1.2-63.7+48.7-15.0-5.0+0.0-18.82.899
1^3P_02.576+6.2-124.9+49.4-75.6-25.5+0.0-94.82.481
1^1P_12.565-14.7+0.0+0.0+0.0+0.0+0.0-14.72.547
1^3P_12.566+5.0-55.9+25.3-30.6+11.7+0.0-13.92.554
1^3P_22.567+3.7+48.1-25.9+22.3-2.1+0.0+23.92.591
1^3D_32.915+0.8+35.5-33.6+1.9-1.2+0.0+1.52.916
1^3F_43.201+0.3+26.1-36.4-10.4-0.7+0.0-10.83.190

Fine-Structure Mass Convention (audit note) ​

Unequal-mass diagonal fine structure still uses the symmetric L·S contraction. Same-J ^1L_J/^3L_J rows are then corrected by the antisymmetric spin-orbit block when both partner rows are present; other unequal-mass rows remain under the symmetric convention.

statem1 GeVm2 GeVconvention
1^1S_01.6280000.220000disabled
2^1S_01.6280000.220000disabled
1^3S_11.6280000.220000disabled
2^3S_11.6280000.220000disabled
1^3D_11.6280000.220000unequal_mass_equal_share_LdotS
1^3P_01.6280000.220000unequal_mass_equal_share_LdotS
1^1P_11.6280000.220000unequal_mass_same_j_mixed
1^3P_11.6280000.220000unequal_mass_same_j_mixed
1^3P_21.6280000.220000unequal_mass_equal_share_LdotS
1^3D_31.6280000.220000unequal_mass_equal_share_LdotS
1^3F_41.6280000.220000unequal_mass_equal_share_LdotS
1^1S_01.6280000.419000disabled
2^1S_01.6280000.419000disabled
1^3S_11.6280000.419000disabled
2^3S_11.6280000.419000disabled
1^3D_11.6280000.419000unequal_mass_equal_share_LdotS
1^3P_01.6280000.419000unequal_mass_equal_share_LdotS
1^1P_11.6280000.419000unequal_mass_same_j_mixed
1^3P_11.6280000.419000unequal_mass_same_j_mixed
1^3P_21.6280000.419000unequal_mass_equal_share_LdotS
1^3D_31.6280000.419000unequal_mass_equal_share_LdotS
1^3F_41.6280000.419000unequal_mass_equal_share_LdotS

Same-J Antisymmetric Spin-Orbit Mixing ​

Rows below use the mixed eigenvalues from the (^1L_J, ^3L_J) mass block. Components are ordered as singlet/triplet in the unmixed basis.

stateunmixed GeVmixed GeVoffdiag MeVtheta degsinglet componenttriplet component
1^1P_12.4572.456+3.7-25.79+0.900-0.435
1^3P_12.4632.465+3.7-25.79+0.435+0.900
1^1P_12.5502.547+3.5-39.56+0.771-0.637
1^3P_12.5522.554+3.5-39.56+0.637+0.771

Same-J Tensor Mixing ​

Rows below use the mixed eigenvalues from triplet L=J-1 / L=J+1 tensor blocks. Components are ordered as lower-L/higher-L in the unmixed basis.

stateunmixed GeVmixed GeVoffdiag MeVlower-L componenthigher-L component
2^3S_12.6452.645+3.4+1.000-0.020
1^3D_12.8162.816+3.4+0.020+1.000
2^3S_12.7352.735+2.8+1.000-0.017
1^3D_12.8982.899+2.8+0.017+1.000

Mean absolute residual: 6.1 MeV. Max absolute residual: 24.8 MeV.

Spin-Averaged Diagnostics ​

Weighted by 2J+1 within each available (n, L) group.

multipletstatesreference GeVbaseline GeVresidual MeV
1D42.8702.869-1.1
1F23.1503.151+1.4
1P82.5182.517-0.4
1S42.0462.042-4.2
2S42.6702.675+4.5

The spin-independent central path is the current GI reproduction candidate. Remaining heavy-quarkonium residuals should be read mainly as spin-dependent/operator-ordering and extraction-audit targets.